Shiki is good in her own right. Currently her competitor is Emiya dad who is also an art-based ST assassin. Not sure if you wanna count the coming-soon Shuten, she is art-based AOE.
Being a welfare servant, Shiki NP5 is easily achieveable whereas Emiya needs more investment to do the same amount of damage. Both have evade, crit boost, invinc.pierce, art boost and good star gen which are all very nice to have. Also, I have found Shiki's insta death niche to be extremely useful, less so for Emiya's target taunt which requires more specific set-up.
Overall, i'd stick with Shiki in foreseeable future.
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