There are two ideas you can go with when it comes to grail ascension. The most popular is to just grail servants you personally like, because the stat boost from grail ascension is not really all that huge. The other is to grail your good 4* servants to 90, because that's probably the most optimal use from a min-max perspective. The least optimal thing you can do is grail a 5* servant to 100, because past level 90 you only get 2 levels per grail instead of 5, but if the servant you like is a 5* then go for it.
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