The overcharge percentage doesn't affect damage; NP level does. An NP2 on Ozy for example, even at 100% charge will deal more damage than NP1 Ozy. Placement order (which order the cards are selected) have no affect on NPs, so in most cases it's best to put them first in a chain.
Overcharge only affects the additional effect that NPs have. In Ozy's case, an overcharge of 200% will reduce the opponent's defence by 30% instead of the 20% at 100% charge.
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