1. Shuten and Orion work fairly well together both being arts focused servants and Orion being a decent crit user goes well with any assassin I wouldn't call it the greatest combination every but its definitely solid. Both of the defiantly go on an arts team and I would suggest a support Waver(Lord El Melloi II) as the final character for such a front line. Worth noting Orion/Tamamo/Waver is one of the games stronger bossing teams(especially against males) should you ever get tamamo/waver you could fill the other with support.
As for Ushi the problem you'll run into is that the rider class has a higher crit star pull than archers so she'll end up stealing most of the stars that you want to be going to Orion who can use them more effectively.
As for NP level its *only* level that effects damage in most cases overcharge has other effects -pre interlude orion's NP1 does 900% NP2 does 1200% and raising overload increases the chance of decreasing the targets charge. Post interlude NP1 does 1200% NP2 does 1500% and increasing overcharge decreases the opponents crit chance.
3.I would recommend getting a few servants up to max level so you can participate in events effectively then do story - story gives you a large number of saint quartz and allows for farming important materials for skills/ascension also some events require you to be at a certain part of the story to participate .
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